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Anna Atkins (1799-1864) was the first artist to produce a book illustrated with cyanotypes. Here is a contact print of ferns that she made from a fern she gathered in the Great Conservatory of Chatsworth on 26 August 1851 (Private collection).
To learn more about the cyanotype process refer to:
http://en.wikipedia.org/wiki/Cyanotype
http://www.photography.com/articles/history/cyanotype/
To see how easy it is to make a cyanotype look at this set of YouTube tutorials:
http://www.youtube.com/results?search_query=cyanotype&aq=f
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